Infrared imaging spectroscopy with micron resolution of Sutter's Mill meteorite grains     

Mehmet Yesiltas  Yoko Kebukawa  Robert E. Peale  Eric Mattson  Carol J. Hirschmugl  Peter Jenniskens 《Meteoritics & planetary science》2014,49(11):2027-2037

Synchrotron‐based Fourier transform infrared spectroscopy and Raman spectroscopy are applied with submicrometer spatial resolution to multiple grains of Sutter's Mill meteorite, a regolith breccia with CM1 and CM2 lithologies. The Raman and infrared active functional groups reveal the nature and distribution of organic and mineral components and confirm that SM12 reached higher metamorphism temperatures than SM2. The spatial distributions of carbonates and organic matter are negatively correlated. The spatial distributions of aliphatic organic matter and OH relative to the distributions of silicates in SM2 differ from those in SM12, supporting a hypothesis that the parent body of Sutter's Mill is a combination of multiple bodies with different origins. The high aliphatic CH₂/CH₃ ratios determined from band intensities for SM2 and SM12 grains are similar to those of IDPs and less altered carbonaceous chondrites, and they are significantly higher than those in other CM chondrites and diffuse ISM objects.  相似文献   

Bulk organic δ13C and C/N ratios as palaeosalinity indicators within a Scottish isolation basin     

Elizabeth A. V. Mackie  Melanie J. Leng  Jeremy M. Lloyd  Carol Arrowsmith 《第四纪科学杂志》2005,20(4):303-312

Microfossils in isolation basin sediments are frequently used to reconstruct sea‐level change, but preservation problems and non‐analogue situations can limit their usefulness. Here we investigate the potential of stable carbon isotopes (δ¹³C) and C/N ratios from bulk organic matter, as an alternative proxy of salinity within isolation basin sediments from a basin in northwest Scotland. Within the Holocene sediment δ¹³C and C/N are determined largely by the mean weighted values of the predominant source of the organic material. Analysis of modern materials and comparison with the diatom record shows that the marine parts of the sequence are dominated by high δ¹³C and variable C/N. In the fresh water sequences the organic material is a mixture of both freshwater aquatic and terrestrial plant input that have relatively low δ¹³C and high C/N. The application of δ¹³C and C/N ratios in the studied basin in general follow the environmental change recorded by the diatoms and shows the potential of bulk organic matter in the investigation of salinity change in isolation basins. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Observations of the infrared triplet of singly ionized calcium     

Jeffrey L. Linsky  Richard G. Teske  Carol W. Wilkinson 《Solar physics》1970,11(3):374-383

Observations are presented of the Caii infrared triplet (8498 Å, 8542 Å, and 8662 Å) at three positions on the solar disk to make possible direct analyses of the lines and comparisons with theoretical computations. The source functions for the two strongest lines (8542 Å and 8662 Å) are equal at those heights corresponding to the wings of the lines (¦¦ > 0.4 Å) but not to those of the cores. We suggest that the apparent source function inequality in the cores is due to limb darkening caused by inhomogeneities in the chromosphere.Of the National Bureau of Standards and University of Colorado.  相似文献   

Strontium isotopic identification of water-rock interaction and ground water mixing   总被引：1，自引：0，他引：1  

Frost CD  Toner RN 《Ground water》2004,42(3):418-432

87Sr/86Sr ratios of ground waters in the Bighorn and Laramie basins' carbonate and carbonate-cemented aquifer systems, Wyoming, United States, reflect the distinctive strontium isotope signatures of the minerals in their respective aquifers. Well water samples from the Madison Aquifer (Bighorn Basin) have strontium isotopic ratios that match their carbonate host rocks. Casper Aquifer ground waters (Laramie Basin) have strontium isotopic ratios that differ from the bulk host rock; however, stepwise leaching of Casper Sandstone indicates that most of the strontium in Casper Aquifer ground waters is acquired from preferential dissolution of carbonate cement. Strontium isotope data from both Bighorn and Laramie basins, along with dye tracing experiments in the Bighorn Basin and tritium data from the Laramie Basin, suggest that waters in carbonate or carbonate-cemented aquifers acquire their strontium isotope composition very quickly--on the order of decades. Strontium isotopes were also used successfully to verify previously identified mixed Redbeds-Casper ground waters in the Laramie Basin. The strontium isotopic compositions of ground waters near Precambrian outcrops also suggest previously unrecognized mixing between Casper and Precambrian aquifers. These results demonstrate the utility of strontium isotopic ratio data in identifying ground water sources and aquifer interactions.  相似文献   

Using the geologic setting of talc deposits as an indicator of amphibole asbestos content   总被引：1，自引：0，他引：1  

Bradley?S.?Van GosenEmail author  Heather?A.?Lowers  Stephen?J.?Sutley  Carol?A.?Gent 《Environmental Geology》2004,45(7):920-939

This study examined commercial talc deposits in the U.S. and their amphibole-asbestos content. The study found that the talc-forming environment directly influenced the amphibole and amphibole-asbestos content of the talc deposit. Large talc districts in the U.S. have mined hydrothermal talcs that replaced dolostone. Hydrothermal talcs, created by siliceous fluids heated by magmas at depth, consistently lack amphiboles as accessory minerals. In contrast, mineable talc deposits that formed by contact or regional metamorphism consistently contain amphiboles, locally as asbestiform varieties. Examples of contact metamorphic deposits occur in Death Valley, California; these talc-tremolite deposits contain accessory amphibole-asbestos. Talc bodies formed by regional metamorphism always contain amphiboles, which display a variety of compositions and habits, including asbestiform. Some industrial mineral deposits are under scrutiny as potential sources of accessory asbestos minerals. Recognizing consistent relations between the talc-forming environment and amphibole-asbestos content may be used in prioritizing remediation or monitoring of abandoned and active talc mines.  相似文献   

Genetic techniques for livestock breeding: Restructuring institutional relationships in agriculture     

David Gibbs  Lewis Holloway  Ben Gilna  Carol Morris 《Geoforum》2009,40(6):1041-1049

This paper explores some of the key institutional transformations in livestock breeding associated with the increasing significance of genetic techniques, situating this within an assessment of an emerging agricultural bioeconomy. Focusing on beef cattle and sheep breeding in the United Kingdom, the paper examines how a move towards the involvement of international and corporate interests in livestock breeding is restructuring the network of institutional interests affecting the knowledge and decision making of individual breeders. The paper suggests that the structural transformation of beef cattle and sheep breeding is complicated by the need for negotiation between breeders’ ‘traditional’ knowledge-practices and the ‘geneticised’ techniques being made available to them. We are thus seeing the emergence of new and complex interactions between the major actors which are reconfiguring power relationships in the UK livestock breeding sector.  相似文献   

Comparison of laboratory testing protocols to field observations of the weathering of sulfide-bearing mine tailings   总被引：1，自引：0，他引：1  

Carla Ardau  David W. Blowes  Carol J. Ptacek 《Journal of Geochemical Exploration》2009,100(2-3):182-191

A laboratory weathering study using a humidity cell procedure was conducted on two sulfide-bearing tailing samples from a metallurgical site in Ontario (Canada). The test was accompanied by microbiological studies to enumerate the major groups of sulfur-oxidizing bacteria and determine their potential role at different stages during the oxidation process. To evaluate the utility of this method, results were compared with those of previous laboratory and field studies on the same materials. The mineralogy of the laboratory samples differs only by the addition of a small amount of hydronium-bearing natrojarosite [(Na,H₃O)Fe₃(SO₄)₂(OH)₆] to one sample. The progress of sulfide oxidation and the rates of solute release were determined to evaluate the extent of mineral dissolution. These processes were influenced strongly by the capacity of the material to generate acidity, which was enhanced by the presence of hydronium-bearing natrojarosite. Acid-neutralization processes occurring during the laboratory tests were affected by reaction kinetics, consistent with field observations. In particular, the extent of carbonate-mineral dissolution appears to be different in the laboratory than in the field, where more prolonged rock–water interaction allowed more complete chemical equilibration. As a consequence, the capacity of this test procedure to predict weathering reactions in mine tailings is limited by its inability to reproduce the weathering sequence observed in the field. The results of the microbiological study showed that distinct groups of sulfur-oxidizing bacteria operate at different stages of the oxidative process, as was observed in field studies where tailings oxidation occurred under natural conditions, suggesting that microbiological tests performed for laboratory studies are reflective of field conditions.  相似文献   

Modern Wyoming plant and pronghorn isoscapes and their implications for archaeology     

Jack N. Fenner  Carol D. Frost 《Journal of Geochemical Exploration》2009,102(3):149

Stable isotope ratios obtained from pronghorn teeth recovered from archaeological sites in southwestern Wyoming may provide information on past climate and hunter behavior. However, the interpretation of archaeological isotope values depends on pronghorn isotopic correlations with the environment and geography. To investigate these correlations, a series of modern Wyoming carbon, oxygen and strontium isoscapes are compared with recent temperature, humidity and geological variation. Results indicate that both pronghorn and sagebrush carbon, and to a lesser degree oxygen, isotope ratios are tied to relative humidity. Temperature is correlated with oxygen isotope ratios in sagebrush, but not pronghorn. Strontium isotope ratios in both sagebrush and pronghorn vary with geography, which in turn reflects variation in geology.  相似文献   

Pilot study experiments sourcing quartzite,Gunnison Basin,Colorado     

Bonnie L. Pitblado  Carol Dehler  Hector Neff  Stephen T. Nelson 《Geoarchaeology》2008,23(6):742-778

This paper reports the results of pilot‐study efforts to develop methods to profile quartzite, a rock type to which geochemical and other sourcing techniques have only rarely been applied. The long‐term goal of the research is to fingerprint sources of quartzite in the Gunnison Basin, southwest Colorado, used by Paleoindian people ca. 11,500–8,000 years ago to make stone tools. Success would facilitate reconstruction of Paleoindian mobility in the Southern Rocky Mountains and potentially anywhere prehistoric people used quartzite. The goals of this paper are more modest: to demonstrate that a small‐scale exploration of sourcing techniques suggests reason for optimism that quartzites may be amenable to source discrimination. For the same twenty Gunnison Basin quartzite samples, this study evaluated petrography, ultraviolet fluorescence (UVF), wavelength dispersive X‐ray fluorescence (WD‐XRF), instrumental neutron activation analysis (INAA), and inductively coupled plasma mass spectrometry—both acid‐digestion (AD‐ICP‐MS) and laser ablation (LA‐ICP‐MS)—as means to differentiate among the specimens and the sources they represent. Although more testing is needed to verify and refine our results, the study suggests there is potential for petrography, INAA, and both versions of ICP‐MS to discriminate among quartzites from different source localities in the Gunnison Basin. The greatest potential for discriminating among different sources of quartzite in the Gunnison Basin may lie in a methodology combining petrographic analysis and LA‐ICPMS. Future testing is required to evaluate this two‐fold approach. © 2008 Wiley Periodicals, Inc.  相似文献   

Effects of intensive aquifers exploitation on groundwater salinity in coastal wetlands     

Malva Mancuso  Lucía Santucci  Eleonora Carol 《水文研究》2020,34(11):2313-2323

The coastal plain of the Río de la Plata constitutes a large wetland which develops on the right margin of the river estuary. Anthropic activities such as intensive exploitation of groundwater carried out in the vicinity of the wetland can modify the natural hydrological regime. The aim of this work is to asses the effects of intensive aquifer exploitation in coastal wetlands using hydrogeological models. Such models allow to evaluate changes in the environmental conditions of wetland at regional level. The hydrogeological model exposed in this work shows how the intensive groundwater exploitation affects the wetland area, generating important variations both in the groundwater flows and in the salinity of the groundwater. Identification of these modifications to the environment is important to generate guidelines leading to minimize these affectations.  相似文献